|
Scale
|
|
|
Sulfuric acid1N.................................................................
0.3
|
Blood, human..............................................................
7.3 -7.5
|
|
Limes.................................................................................
2.0
|
Egg White ..................................................................7.6
- 8.0
|
|
Wines........................................................................
2.8 - 3.8
|
Sodium Bicarbonate...........................................................
8.4
|
|
Oranges....................................................................
3.0 to 4.0
|
Ammonia 1N ....................................................................11.6
|
|
Beers........................................................................
4.0 to 5.0
|
Lime, saturated .................................................................12.4
|
|
Cheese.....................................................................
4.8 to 6.4
|
Caustic Soda....................................................................
14.0
|
pH= log (H
+)
The pH value of an aqueous solution is directly related to the hydrogen (H+) and hydroxyl (OH-) ion concentrations. Acids are those substances which break down to give hydrogen ions while bases break down to give hydroxyl ions. If the OH- concentration is greater than the H+ concentration, the solution is alkaline and will have a pH greater than7. If the H+concentration is greater than the OH- concentration the solution is acidic and will have a pH less than 7. Solutions with an equal amount of H+ ions and OH- ions are neutral and have a pH of 7. In a neutral solution we have the following situation:
(H+) x (OH-)=10-7x10-7=10-14
In all solutions the product of H+and OH- is a constant. That is it the concentration of H+ions increase the concentration of OH-ions must decrease but the product will remain at 1 x 10-14.
|
pH scale
|
||||||
|
Molar hydrogen ion concentration (H+)
|
pH |
Molar hydroxyl ion concentration (OH-)
|
||||
| 100 | 1.0 | 0 |
|
0.00000000000001 | 10-14 | |
| 10-1 | 0.1 | 1 | 0.0000000000001 | 10-13 | ||
| 10-2 | 0.01 | 2 | More | 0.000000000001 | 10-12 | |
| 10-3 | 0.001 | 3 | acidic | 0.00000000001 | 10-11 | |
| 10-4 | 0.0001 | 4 | 0.0000000001 | 10-10 | ||
| 10-5 | 0.00001 | 5 | 0.000000001 | 10-9 | ||
| 10-6 | 0.000001 | 6 | 0.00000001 | 10-8 | ||
| 10-7 | 0.0000001 | 7 | Neutral | 0.0000001 | 10-7 | |
| 10-8 | 0.00000001 | 8 |
|
0.000001 | 10-6 | |
| 10-9 | 0.000000001 | 9 | 0.00001 | 10-5 | ||
| 10-10 | 0.0000000001 | 10 | More | 0.0001 | 10-4 | |
| 10-11 | 0.00000000001 | 11 | alkaline | 0.001 | 10-3 | |
| 10-12 | 0.000000000001 | 12 | 0.01 | 10-2 | ||
| 10-13 | 0.0000000000001 | 13 | 0.1 | 10-1 | ||
| 10-14 | 0.00000000000001 | 14 | 1.0 | 100 | ||
The pH scale shows the active hydrogen ion and hydroxyl ion
concentrations.
The more hydrogen ions present in solution
the lower the pH and the more acidic the solution. A solution of pH 1.0
is one million times more acidic than one of pH 7.0. Equal amounts of hydrogen
and hydroxyl ions are present at pH 7.0. It can be seen that above pH 7.0, the
hydrogen ion concentration becomes insignificantly small because the hydroxyl
ion concentration become dominant.
Note that each pH unit differs from the one above or below it by a factor of
ten. Each change in one pH unit corresponds to a tenfold
change in hydrogen ion or hydroxyl ion concentration. Thus a solution at pH
5.0 will have ten times more active hydrogen ions than a solution of pH 6.0.
The hydrogen ion activity is expressed in moles per liter because in aqueous
solutions (H+) concentration is one ten millionth moles per liter,
or 10-7 molar.